Issue 16, 2000
From the journal:

Chemical Communications

Self- and hetero-recognition in the guest-controlled assembly of Pd(ii)-linked cages from two different ligands

Shuichi Hiraoka,†a   Yasuo Kubotaa  and  Makoto Fujita*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, CREST, Japan Science and Technology Cooperation (JST), Chikusa, Nagoya, Japan.
E-mail: mfujita@apchem.nagoya-u.ac.jp

Abstract

The equilibration of cage-like receptors, M3(L1)2 + M3(L2)2 ⇌ 2 M3(L1)(L2), was efficiently controlled by appropriate guest addition: large (spherical) or small (flat) guests stabilized the homoleptic cages (M3(L1)2 or M3(L2)2) while medium-sized guests preferred the heteroleptic cage (M3(L1)(L2)).

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Article information

DOI
https://doi.org/10.1039/B004271O
Article type
Communication
Submitted
30 May 2000
Accepted
27 Jun 2000
First published
21 Jul 2000

Chem. Commun., 2000, 1509-1510

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Self- and hetero-recognition in the guest-controlled assembly of Pd(II)-linked cages from two different ligands

S. Hiraoka, Y. Kubota and M. Fujita, Chem. Commun., 2000, 1509 DOI: 10.1039/B004271O

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