Issue 17, 2000

Alcohol induced stereospecific P–C bond cleavage to afford Ru–phenyl derivatives containing three different types of stereogenicity: novel and unprecedented complexes of P(OH)(OR)Ph

Abstract

Alcohol induced stereospecific P–C bond cleavage in a Ru–P(OH)Ph2 fragment affords new chiral-Binap and MeO-Biphep based complexes containing three different forms of stereogenicity: ligand atropisomerism plus stereogenic Ru and P atoms; these represent the first reported transition metal complexes of the ligands P(OH)(OR)Ph.

Article information

Article type
Communication
Submitted
31 May 2000
Accepted
19 Jul 2000
First published
10 Aug 2000

Chem. Commun., 2000, 1629-1630

Alcohol induced stereospecific P–C bond cleavage to afford Ru–phenyl derivatives containing three different types of stereogenicity: novel and unprecedented complexes of P(OH)(OR)Ph

T. J. Geldbach, D. Drago and P. S. Pregosin, Chem. Commun., 2000, 1629 DOI: 10.1039/B004385K

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