2-O-Allyl protected glycosyl donors may be glycosylated stereoselectively via a three step sequence involving double bond isomerization, N-iodosuccinimide mediated tethering to a glycosyl acceptor and subsequent intramolecular glycosylation (intramolecular aglycon delivery, IAD).
Stereoselective cis glycosylation of 2-O-allyl protected glycosyl donors by intramolecular aglycon delivery (IAD)
C. M. P. Seward, I. Cumpstey, M. Aloui, S. C. Ennis, A. J. Redgrave and A. J. Fairbanks, Chem. Commun., 2000, 1409 DOI: 10.1039/B004522P
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