Issue 2, 2001
From the journal:

Chemical Communications

Triple-decker main group cationsElectronic supplementary information (ESI) available: summary of theoretical data. See http://www.rsc.org/suppdata/cc/b0/b005425i/

Alan H. Cowley,*a   Charles L. B. Macdonald,a   Joel S. Silverman,a   John D. Gordena  and  Andreas Voigta  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas, USA.
E-mail: cowley@mail.utexas.edu

Abstract

The syntheses of the first main group triple-decker cations are described, namely, [(η5-C5Me5)Sn(μ-η5- C5Me5)Sn(η5-C5Me5 )][Ga(C6F5)4] and [(η6-C7H8)In(μ-η5-C 5Me5)In(η6-C7H8 )][(C6F5)3BO(H)B(C6F 5)3], both of which have been characterized by X-ray crystallography; the former was prepared by the reaction of Sn(η5-C5Me5)2 with Ga(C6F5)3, while the latter was prepared by treatment of [In(η5-C5Me5)]6 with an equimolar mixture of B(C6F5)3 and H2O·B(C6F5)3.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B005425I
Article type
Communication
Submitted
16 Jun 2000
Accepted
27 Nov 2000
First published
08 Jan 2001

Chem. Commun., 2001, 175-176

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Triple-decker main group cations

A. H. Cowley, C. L. B. Macdonald, J. S. Silverman, J. D. Gorden and A. Voigt, Chem. Commun., 2001, 175 DOI: 10.1039/B005425I

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