Issue 24, 2000
From the journal:

Chemical Communications

A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex

Carsten Bolm,*a   Nico Meyer,a   Gerhard Raabe,a   Thomas Weyhermüllerb  and  Eberhard Botheb  

* Corresponding authors

a Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Straße 1, D-52056, Aachen, Germany.
E-mail: Carsten.Bolm@oc.rwth-aachen.de;
Fax: Fax: (+49) 241 8888 391

b Max-Planck-Institut für Strahlenchemie, Stiftstr. 34-36, D-45470, Mülheim an der Ruhr, Germany

Abstract

The X-ray crystal structure and electrochemical data of a manganese complex [L2Mn2III(μ-O)(μ-AcO)2][ PF6]2 with L being an enantiopure C3-symmetric 1,4,7-triazacyclononane derived from L-proline are compared to those of [Me3- TACN2Mn2III(μ-O)(μ-AcO)2 ][PF6]2; catalytic studies reveal the applicability of the complex in enantioselective epoxidations.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B007059I
Article type
Communication
Submitted
30 Aug 2000
Accepted
26 Oct 2000
First published
23 Nov 2000

Chem. Commun., 2000, 2435-2436

Permissions

Request permissions

A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex

C. Bolm, N. Meyer, G. Raabe, T. Weyhermüller and E. Bothe, Chem. Commun., 2000, 2435 DOI: 10.1039/B007059I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements