Oxidation of water-insoluble alcohols in supercritical CO2 over a Pd–Pt–Bi/C catalyst in a continuous fixed bed reactor affords high reaction rates and yields up to 98% of the corresponding ketones, aromatic and α,β-unsaturated aliphatic aldehydes, without the risk of using a flammable organic solvent.
Partial oxidation of alcohols in supercritical carbon dioxide
G. Jenzer, D. Sueur, T. Mallat and A. Baiker, Chem. Commun., 2000, 2247 DOI: 10.1039/B007114P
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