Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kink

Andrzej Rajca; Hua Wang; Visa Pawitranon; Tom J. Brett; John J.  Stezowski

doi:10.1039/B007355P

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Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kinkElectronic supplementary information (ESI) available: synthesis and characterization data for 1, 2, 4, and 5; crystal packing plots for rac-1. See http://www.rsc.org/suppdata/cc/b0/b007355p/

Andrzej Rajca,*^a Hua Wang,^a Visa Pawitranon,^a Tom J. Brett^a and John J. Stezowski^a

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^a Department of Chemistry and Center for Materials Research and Analysis, University of Nebraska, Lincoln, NE, USA.
E-mail: arajcal@unl.edu

Abstract

A chiral oligothiophene, possessing in-chain chirality, was prepared and its racemate was characterized by single crystal X-ray crystallography; the in-chain chiral 1,1′-binaphthyl moiety interrupts the π-conjugation and affects the solid state properties of the oligothiophene.

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DOI: https://doi.org/10.1039/B007355P
Article type: Communication
Submitted: 14 Aug 2000
Accepted: 10 Apr 2001
First published: 22 May 2001

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Chem. Commun., 2001, 1060-1061

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Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kink

A. Rajca, H. Wang, V. Pawitranon, T. J. Brett and J. J. Stezowski, Chem. Commun., 2001, 1060 DOI: 10.1039/B007355P

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Chemical Communications

Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kinkElectronic supplementary information (ESI) available: synthesis and characterization data for 1, 2, 4, and 5; crystal packing plots for rac-1. See http://www.rsc.org/suppdata/cc/b0/b007355p/

Abstract

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Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kink

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