Issue 12, 2000
From the journal:

New Journal of Chemistry

Synthesis and characterisation of a bridging nitrido complex of titanium

Claire J. Carmalt,*a   John D. Mileham,a   Andrew J. P. Whiteb  and  David J. Williamsb  

* Corresponding authors

a Department of Chemistry, Christopher Ingold Laboratories, Uniersity College London, 20 Gordon Street, London
E-mail: c.j.carmalt@ucl.ac.uk

b Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London

Abstract

Titanium tetrachloride reacts with hexamethyldisilazane in the presence of 3,5-dimethylpyridine (L) to form a bridging nitrido species, [{Ti2Cl5(L)5}(μ-N)], the structure of which has been established by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/B008211M
Article type
Letter
Submitted
02 Aug 2000
Accepted
10 Oct 2000
First published
08 Nov 2000

New J. Chem., 2000,24, 929-930

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Synthesis and characterisation of a bridging nitrido complex of titanium

C. J. Carmalt, J. D. Mileham, A. J. P. White and D. J. Williams, New J. Chem., 2000, 24, 929 DOI: 10.1039/B008211M

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