Issue 3, 2001

[(thf )6Ba6(dmpz)8{(OSiMe2)2O}2] (dmpz = 3,5-dimethylpyrazolate): a molecule with six barium cations in a plane capped by two siloxane dianions and framed by eight dmpz anions

Abstract

In the synthesis of barium 3,5-dimethylpyrazolate, silicone joint grease and cyclo-(Me2SiO)4 are cleaved and two O(SiMe2O)22− bidentate chelating siloxane anions are coordinated above and below an unprecedented Ba612− layer framed by eight σ/π coordinated pyrazolate anions.

Graphical abstract: [(thf [ ] )6Ba6(dmpz)8{(OSiMe2)2O}2] (dmpz = 3,5-dimethylpyrazolate): a molecule with six barium cations in a plane capped by two siloxane dianions and framed by eight dmpz anions [ ]

Supplementary files

Article information

Article type
Communication
Submitted
14 Nov 2000
Accepted
20 Dec 2000
First published
12 Jan 2001

J. Chem. Soc., Dalton Trans., 2001, 219-221

[(thf )6Ba6(dmpz)8{(OSiMe2)2O}2] (dmpz = 3,5-dimethylpyrazolate): a molecule with six barium cations in a plane capped by two siloxane dianions and framed by eight dmpz anions

A. Steiner, G. T. Lawson, B. Walfort, D. Leusser and D. Stalke, J. Chem. Soc., Dalton Trans., 2001, 219 DOI: 10.1039/B009121I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements