Issue 9, 2001
From the journal:

Chemical Communications

Induced assembly of a catenated chain of edge-sharing silver(i) dodecahedra with embedded acetylide by silver(ii)-tmc (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)

Quan-Ming Wanga  and  Thomas C. W. Mak*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P.R. China.
E-mail: tcwmak@cuhk.edu.hk

Abstract

In the mixed-valent complex [AgII(tmc)(BF4)][AgI6(C2 )(CF3CO2)5(H2O)]· H2O, a [AgII(tmc)(BF4)]+1∞ cationic column induces the assembly of a novel, anionic zigzag chain constructed from edge-sharing of silver(I) triangulated dodecahedra each enclosing a C22− species.

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Article information

DOI
https://doi.org/10.1039/B009765I
Article type
Communication
Submitted
06 Dec 2000
Accepted
12 Mar 2001
First published
09 Apr 2001

Chem. Commun., 2001, 807-808

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Induced assembly of a catenated chain of edge-sharing silver(I) dodecahedra with embedded acetylide by silver(II)-tmc (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)

Q. Wang and T. C. W. Mak, Chem. Commun., 2001, 807 DOI: 10.1039/B009765I

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