Issue 4, 2001
From the journal:

New Journal of Chemistry

First synthesis and crystal structure of a Mn3+ complex derived from the Ogawa porphyrin-like ligand

Céline Pierre,a   Jean-Marc Vincent,*a   Jean-Baptiste Verlhac,*a   Christian Courseille,b   Alain Dautantb  and  Corinne Mathonierec  

* Corresponding authors

a Laboratoire de Chimie Organique et Organométallique (CNRS UMR 5802), Uniersité Bordeaux I, 351 cours de la Libération, Talence cedex, France
E-mail: j-b.verlhac@lcoo.u-bordeaux.fr

b Unité de Biophysique Structurale (CNRS UMR 5471), Uniersité Bordeaux I, aenue des Facultés, Talence cedex, France

c Institut de Chimie de la Matière Condensée de Bordeaux (CNRS UPR 9048), 87 aenue du Dr Albert Schweitzer, Pessac cedex, France

Abstract

The synthesis and X-ray structure analysis of a new manganese(III) complex [MnL1(H2O)2]OTf displaying structural analogies with metalloporphyrins are described. This compound is characterized by very short Mn–N bond distances (1.93 Å) and a nearly planar structure. Its ability to catalyze cyclohexene epoxidation in the presence of MCPBA has also been evaluated.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B100169H
Article type
Letter
Submitted
29 Dec 2000
Accepted
06 Feb 2001
First published
14 Mar 2001

New J. Chem., 2001,25, 522-524

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First synthesis and crystal structure of a Mn3+ complex derived from the Ogawa porphyrin-like ligand

C. Pierre, J. Vincent, J. Verlhac, C. Courseille, A. Dautant and C. Mathoniere, New J. Chem., 2001, 25, 522 DOI: 10.1039/B100169H

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