Issue 13, 2001
From the journal:

Chemical Communications

Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium

Ned J. Hardmana  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, CA, USA.
E-mail: pppower@ucdavis.edu

Abstract

The reaction between {HC(MeCDippN)2}Ga: (Dipp = C6H3Pri2 -2,6) and N3SiMe3 afforded the tetrazole {HC(MeCDippN)2}[upper bond 1 start]GaN(SiMe3)NNN[upper bond 1 end](SiMe3) 1 and its amide/azide isomer {HC(MeCDippN)2}Ga(N3)N(SiMe3) 2 2 whose stabilities are due to the unique steric properties of the [HC(MeCDippN)2]− ligand.

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Article information

DOI
https://doi.org/10.1039/B100466M
Article type
Communication
Submitted
01 Jan 2001
Accepted
03 May 2001
First published
13 Jun 2001

Chem. Commun., 2001, 1184-1185

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Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium

N. J. Hardman and P. P. Power, Chem. Commun., 2001, 1184 DOI: 10.1039/B100466M

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