An unusual abrupt thermal spin-state transition in [FeL2][BF4]2 [L = 2,6-di(pyrazol-1-yl)pyridine]

Joanne M. Holland; Judith A. McAllister; Zhibao Lu; Colin A. Kilner; Mark Thornton-Pett; Malcolm A. Halcrow

doi:10.1039/B100995H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

An unusual abrupt thermal spin-state transition in [FeL₂][BF₄]₂ [L = 2,6-di(pyrazol-1-yl)pyridine]Electronic supplementary information (ESI) available: tabulated and plotted unit cell dimensions for 1 between 240–300 K; tabulated magnetic susceptibility data between 10–330 K. See http://www.rsc.org/suppdata/cc/b1/b100995h/

Joanne M. Holland,^a Judith A. McAllister,^b Zhibao Lu,^d Colin A. Kilner,^a Mark Thornton-Pett^a and Malcolm A. Halcrow*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail: M.A.Halcrow@chem.leeds.ac.uk

^b Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK

^c Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge, UK

^d Centre for Self-Organising Molecular Systems, School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK

Abstract

The complex [Fe(L¹H)₂][BF₄]₂ exhibits an abrupt thermal spin-crossover which may be mediated by an order–disorder transition of the BF₄⁻ anions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B100995H
Article type: Communication
Submitted: 29 Jan 2001
Accepted: 15 Feb 2001
First published: 07 Mar 2001

Download Citation

Chem. Commun., 2001, 577-578

Permissions

Request permissions

An unusual abrupt thermal spin-state transition in [FeL₂][BF₄]₂ [L = 2,6-di(pyrazol-1-yl)pyridine]

J. M. Holland, J. A. McAllister, Z. Lu, C. A. Kilner, M. Thornton-Pett and M. A. Halcrow, Chem. Commun., 2001, 577 DOI: 10.1039/B100995H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications