In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Eva Susanne Schmidt; Annette Schier; Hubert Schmidbaur

doi:10.1039/B101016F

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In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Eva Susanne Schmidt,^a Annette Schier^a and Hubert Schmidbaur*^a

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* Corresponding authors

^a Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstrasse 4, Garching, Germany

Abstract

Reduction of cis-ethene-1,2-di(tert-butylamido)gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′-tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η⁵-coordinated to the pseudo-carbene ring system of one monomer and η¹-bonded to the gallium atom of the other.

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Crystal structure data TXT (32K)

Article information

DOI: https://doi.org/10.1039/B101016F
Article type: Communication
Submitted: 27 Nov 2000
Accepted: 30 Jan 2001
First published: 09 Feb 2001

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J. Chem. Soc., Dalton Trans., 2001, 505-507

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In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

E. S. Schmidt, A. Schier and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 2001, 505 DOI: 10.1039/B101016F

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Journal of the Chemical Society, Dalton Transactions

In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Abstract

Supplementary files

Article information

Download Citation

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In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

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