Issue 8, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

The first catena-trihydrogen triphosphide: synthesis and crystal structure of [Na(NH3)5][Na(NH3)3(P3H3)]

Nikolaus Korber*a  and  Jürgen Aschenbrennera  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Regensburg, Universitätsstraße 31, Regensburg, Germany
E-mail: nikolaus.korber@chemie.uni-regensburg.de

Abstract

The reaction of P4 with sodium in liquid ammonia (P ∶ Na ratio 3 ∶ 5) yields crystalline NaNH2 and [Na(NH3)5][Na(NH3)3(P3H3)], which contains all-transcatena-P3H32− stabilised in the ion complex [Na(NH3)3(P3H3)]−.

Graphical abstract: The first catena-trihydrogen triphosphide: synthesis and crystal structure of [Na(NH3)5][Na(NH3)3(P3H3)]

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Article information

DOI
https://doi.org/10.1039/B101533H
Article type
Communication
Submitted
16 Feb 2001
Accepted
13 Mar 2001
First published
23 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 1165-1166

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The first catena-trihydrogen triphosphide: synthesis and crystal structure of [Na(NH3)5][Na(NH3)3(P3H3)]

N. Korber and J. Aschenbrenner, J. Chem. Soc., Dalton Trans., 2001, 1165 DOI: 10.1039/B101533H

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