Issue 13, 2001

The first application of SelectfluorTM in electrophilic fluorination of amines: a new route to –NF2, –NHF, and >NF compounds

Abstract

Reactions of primary amines, RNH2 [R = (CH3)3C–, (CH3)2CH–, CH3(CH2)2–, (CH3)2CHCH2–, CH3(CH2)3–] and secondary amines, R2NH [(R = CH3CH2–, CH3(CH2)2–, (CH3)2CHCH2–], with Selectfluor™ in acetonitrile or DMF or DMA result in formation of the corresponding RNF2, RNHF, and R2NF in high yields.

Article information

Article type
Communication
Submitted
21 Feb 2001
Accepted
18 May 2001
First published
13 Jun 2001

Chem. Commun., 2001, 1196-1197

The first application of SelectfluorTM in electrophilic fluorination of amines: a new route to –NF2, –NHF, and >NF compounds

R. P. Singh and J. M. Shreeve, Chem. Commun., 2001, 1196 DOI: 10.1039/B101689J

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