Issue 13, 2001
From the journal:

Chemical Communications

Condensation of acetonitrile into N-acetimidoylacetamidine promoted by a dinuclear nickel(ii) complexElectronic supplementary information (ESI) available: Table S1: hydrogen bonds in the crystal structure of complex 2·2H2O. See http://www.rsc.org/suppdata/cc/b1/b101893k/Dedicated to Professor Konstantin B. Yatsimirskii on the occasion of his 85th birthday.

Sergey V. Kryatov,a   Alexander Y. Nazarenko,*b   Millicent B. Smitha  and  Elena V. Rybak-Akimova*a  

* Corresponding authors

a Department of Chemistry, Tufts University, Medford, Massachusetts, USA.
E-mail: erybakak@emerald.tufts.edu

b Department of Chemistry, State University of New York, College at Buffalo, Buffalo, New York, USA.
E-mail: nazareay@buffalostate.edu

Abstract

Acetonitrile reacts with a dinuclear nickel(II) complex [Ni2(μ-OH)2(tpa)2](ClO4) 2 [tpa = tris-(2-pyridylmethyl)amine] in solution forming a novel square-planar nickel(II) complex Ni{HN[double bond, length half m-dash]C(Me)–N[double bond, length half m-dash]C(Me)–NH}2.

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Article information

DOI
https://doi.org/10.1039/B101893K
Article type
Communication
Submitted
27 Feb 2001
Accepted
15 May 2001
First published
08 Jun 2001

Chem. Commun., 2001, 1174-1175

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Condensation of acetonitrile into N-acetimidoylacetamidine promoted by a dinuclear nickel(II) complex

S. V. Kryatov, A. Y. Nazarenko, M. B. Smith and E. V. Rybak-Akimova, Chem. Commun., 2001, 1174 DOI: 10.1039/B101893K

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