Issue 12, 2001
From the journal:

Chemical Communications

A novel, zeolite-encapsulated μ3-oxo Co/Mn cluster catalyst for oxidation of para-xylene to terephthalic acid

Suhas A. Chavan,a   D. Srinivasa  and  Paul Ratnasamy*a  

* Corresponding authors

a National Chemical Laboratory, Pune, India.
E-mail: prs@ems.ncl.nes.in

Abstract

Trinuclear, μ3-oxo mixed metal acetato complexes, [CoMn2(μ3-O)(MeCO2)6(py) 3] (py = pyridine) encapsulated in zeolite HY, exhibit high catalytic efficiency in the selective aerial oxidation of para-xylene to terephthalic acid; interestingly, the formation of 4-carboxybenzaldehyde, the worrisome impurity in the conventional process, is suppressed significantly over these solid catalysts.

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Article information

DOI
https://doi.org/10.1039/B102016C
Article type
Communication
Submitted
02 Mar 2001
Accepted
10 May 2001
First published
31 May 2001

Chem. Commun., 2001, 1124-1125

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A novel, zeolite-encapsulated μ3-oxo Co/Mn cluster catalyst for oxidation of para-xylene to terephthalic acid

S. A. Chavan, D. Srinivas and P. Ratnasamy, Chem. Commun., 2001, 1124 DOI: 10.1039/B102016C

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