Issue 15, 2001
From the journal:

Chemical Communications

Synthesis and structure of N-heterocyclic carbene complexes of uranyl dichloride

Warren J. Oldham, Jr.,*a   Susan M. Oldham,a   Brian L. Scott,b   Kent D. Abney,b   Wayne H. Smitha  and  David A. Costa*a  

* Corresponding authors

a Nuclear Materials and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
E-mail: woldham@lanl.gov; dcosta@lanl.gov

b Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

Treatment of UO2Cl2(thf)3 in THF with two equivalents of 1,3-dimesitylimidazole-2-ylidene (IMes) or 1,3-dimesityl-4,5-dichloroimidazole-2-ylidene (IMesCl2) yields novel monomeric uranyl N-heterocyclic carbene complexes, representing the first examples of actinyl carbon bonds.

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Article information

DOI
https://doi.org/10.1039/B102649F
Article type
Communication
Submitted
21 Mar 2001
Accepted
13 Jun 2001
First published
05 Jul 2001

Chem. Commun., 2001, 1348-1349

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Synthesis and structure of N-heterocyclic carbene complexes of uranyl dichloride

W. J. Oldham, Jr., S. M. Oldham, B. L. Scott, K. D. Abney, W. H. Smith and D. A. Costa, Chem. Commun., 2001, 1348 DOI: 10.1039/B102649F

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