Issue 13, 2001

Iridium(iii) complexes of the new tridentate bis(8-quinolyl)silyl (‘NSiN’) ligandElectronic supplementary information (ESI) available: synthetic and crystallographic details for 1–5. See http://www.rsc.org/suppdata/cc/b1/b102821a/

Abstract

Bis(8-quinolyl)methylsilane reacts cleanly with [Ir(coe)2Cl]2 (coe = cyclooctene) to give a complex containing an NSiN tridentate ligand, [Ir(NSiN)(coe)(H)(Cl)]; preliminary reactivity studies indicate that the (NSiN)Ir fragment is chemically robust.

Supplementary files

Article information

Article type
Communication
Submitted
22 Mar 2001
Accepted
16 May 2001
First published
13 Jun 2001

Chem. Commun., 2001, 1200-1201

Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (‘NSiN’) ligand

M. Stradiotto, K. L. Fujdala and T. D. Tilley, Chem. Commun., 2001, 1200 DOI: 10.1039/B102821A

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