Issue 11, 2001

Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene

Abstract

Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4,4′-bipyridine 2 in the presence of m-xylene results in the formation of a 2D brick framework, 3c·2(m-xylene), that possesses nanoscale cavities that host four aromatics as guests in which 1 adopts a ‘T-shaped’ conformation.

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2001
Accepted
25 Mar 2001
First published
09 May 2001

Chem. Commun., 2001, 1034-1035

Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene

L. R. MacGillivray, J. L. Reid and J. A. Ripmeester, Chem. Commun., 2001, 1034 DOI: 10.1039/B102856C

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