Issue 13, 2001
From the journal:

Chemical Communications

Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral ‘light fluorous’ phosphine ligand

Marco Cavazzini,a   Gianluca Pozzi,*a   Silvio Quici,a   David Maillardb  and  Denis Sinou*b  

* Corresponding authors

a Centro CNR Sintesi e Stereochimica di Speciali Sistemi Organici, via Golgi 19, Milano, Italy.
E-mail: gianluca.pozzi@unimi.it;
Fax: +39 02 2663354; Tel: +39 02 2663354

b Laboratoire de Synthèse Asymétrique, UMR UCBL/CNRS 5622, Université Claude Bernard Lyon 1, 43, boulevard du 11 novembre 1918, Villeurbanne, France.
E-mail: sinou@univ-lyon1.fr;
Fax: +33 04 72448160; Tel: +33 04 72446263

Abstract

The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2′-alkoxy-1,1′-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.

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Article information

DOI
https://doi.org/10.1039/B103074B
Article type
Communication
Submitted
04 Apr 2001
Accepted
23 May 2001
First published
14 Jun 2001

Chem. Commun., 2001, 1220-1221

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Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral ‘light fluorous’ phosphine ligand

M. Cavazzini, G. Pozzi, S. Quici, D. Maillard and D. Sinou, Chem. Commun., 2001, 1220 DOI: 10.1039/B103074B

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