Issue 17, 2001
From the journal:

Chemical Communications

Cerium masquerading as a Group 4 element: synthesis, structure and computational characterisation of [CeCl{N(SiMe3)2}3]Electronic supplementary information (ESI) available: further details of calculations relating to 3. See http://www.rsc.org/suppdata/cc/b1/b103634n/

Odile Eisenstein,a   Peter B. Hitchcock,b   Alexander G. Hulkes,b   Michael F. Lappert*b  and  Laurent Maron*c  

* Corresponding authors

a Laboratoire de Structure et de Dynamique des Systèmes Moléculaires et Solides (CNRS UMR 5636), CC 14, Université de Montpellier II, Place Eugène Bataillon, Montpellier cedex 5, France.
E-mail: odile.eisenstein@lsd.univ-montp2.fr

b The Chemistry Laboratory, University of Sussex, Brighton, UK
E-mail: M.F.Lappert@sussex.ac.uk

c Laboratoire de Physique Quantique - IRSAMC (CNRS UMR 5626), Université Paul Sabatier, 118 route de Narbonne, Toulouse, France.
E-mail: laurent.maron@irsamc.ups-tlse.fr

Abstract

Oxidation of the three-coordinate cerium amide [Ce{N(SiMe3)2}3] with TeCl4 in toluene solution yields purple, diamagnetic [CeCl{N(SiMe3)2}3], whose structure has been examined by X-ray crystallographic and computational methods.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B103634N
Article type
Communication
Submitted
24 Apr 2001
Accepted
28 Jun 2001
First published
02 Aug 2001

Chem. Commun., 2001, 1560-1561

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Cerium masquerading as a Group 4 element: synthesis, structure and computational characterisation of [CeCl{N(SiMe3)2}3]

O. Eisenstein, P. B. Hitchcock, A. G. Hulkes, M. F. Lappert and L. Maron, Chem. Commun., 2001, 1560 DOI: 10.1039/B103634N

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