A new architecture, comprising two interpenetrating chains of rings, has been discovered in the first organometallic polyrotaxane; the synthesis combines the techniques of organometallic chemistry, coordination chemistry and self-assembly through hydrogen bonding.
An organometallic polyrotaxane and a new type of polyrotaxane architecture
C. S. A. Fraser, M. C. Jennings and R. J. Puddephatt, Chem. Commun., 2001, 1310 DOI: 10.1039/B103967A
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