Issue 26, 2001

Abstract

A three-dimensional coordination polymer, [(H2O)2Cu(pdc)] 1 (pdc⊕=⊕pyridine-3,5-dicarboxylate), has been rationally designed and synthesized under hydrothermal reaction conditions. The structure is self-assembled from bifunctional pyridinecarboxylates and water molecules. Carboxylate groups in 1 contribute to both covalent and hydrogen bonds. The structure is stabilized by offset arylaryl face–face packing interactions.

Article information

Article type
Paper
Submitted
03 May 2001
Accepted
09 May 2001

CrystEngComm, 2001,3, 111-113

Crystal engineering of a three-dimensional coordination polymer based on both covalent and O–H⋯O hydrogen bonding interactions of bifunctional ligands

J. Y. Lu and V. Schauss, CrystEngComm, 2001, 3, 111 DOI: 10.1039/B103981B

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