Issue 5, 2001
From the journal:

Chemical Society Reviews

Stereoselective coupling of

Aurelio G. Csákÿa  and  Joaquín Plumeta  

a Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040-Madrid, Spain

Abstract

This review summarizes the background and the state of the art of the coupling of the enolates of ketones and carboxylic acid derivatives, focusing on the stereoselectivity of the process. Compared with other synthetic applications of enolates, the stereoselective coupling of these species has been considered less in the literature. Recent developments making use of chiral auxiliaries have put forward the versatility of this procedure for the asymmetric synthesis of 1,4-dicarbonyl compounds.

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Article information

DOI
https://doi.org/10.1039/B104000F
Article type
Review Article
Submitted
03 May 2001
First published
03 Aug 2001

Chem. Soc. Rev., 2001,30, 313-320

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Stereoselective coupling of ketone and carboxylate enolates

A. G. Csákÿ and J. Plumet, Chem. Soc. Rev., 2001, 30, 313 DOI: 10.1039/B104000F

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