Issue 18, 2001

Palladium-catalysed intramolecular annulation of 2-haloanilines and ketones: enolate arylation vs. nucleophilic addition to the carbonyl groupDedicated with great appreciation to Professor Francisco Camps for his contribution to organic chemistry.

Abstract

Two alternative annulation pathways involving either the enolate arylation or the addition to the ketone carbonyl group can operate in the Pd-catalysed intramolecular coupling of 2-haloanilines and ketones.

Graphical abstract: Palladium-catalysed intramolecular annulation of 2-haloanilines and ketones: enolate arylation vs. nucleophilic addition to the carbonyl group

Article information

Article type
Communication
Submitted
28 Jun 2001
Accepted
06 Aug 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1888-1889

Palladium-catalysed intramolecular annulation of 2-haloanilines and ketones: enolate arylation vs. nucleophilic addition to the carbonyl group

D. Solé, L. Vallverdú, E. Peidró and J. Bonjoch, Chem. Commun., 2001, 1888 DOI: 10.1039/B105686G

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