Issue 18, 2001
From the journal:

Chemical Communications

Gallium–boron donor–acceptor bonds

Ned J. Hardman,a   Philip P. Power,*a   John D. Gorden,b   Charles L. B. Macdonaldb  and  Alan H. Cowley*b  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, USA.
E-mail: pppower@ucdavis.edu

b Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas, U.S.A

Abstract

Examples of compounds with gallium–boron donor–acceptor bonds, HC[MeC(2,6-Pri2C6H3)N]2Ga→B(C6F5)33 and (η5-C5Me5)Ga→B(C6F5)34 have been prepared by treatment of the free gallanediyls with B(C6F5)3; the structures of both compounds were determined by X-ray crystallography.

Graphical abstract: Gallium–boron donor–acceptor bonds

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Article information

DOI
https://doi.org/10.1039/B106599H
Article type
Communication
Submitted
19 Jun 2001
Accepted
01 Aug 2001
First published
29 Aug 2001

Chem. Commun., 2001, 1866-1867

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Gallium–boron donor–acceptor bonds

N. J. Hardman, P. P. Power, J. D. Gorden, C. L. B. Macdonald and A. H. Cowley, Chem. Commun., 2001, 1866 DOI: 10.1039/B106599H

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