Fullerene–porphyrin architectures; photosynthetic antenna and reaction center models

Abstract

Fullerenes and porphyrins are molecular architectures ideally suited for devising integrated, multicomponent model systems to transmit and process solar energy. Implementation of C₆₀ as a 3-dimensional electron acceptor holds great expectations on account of their small reorganization energy in electron transfer reactions and has exerted a noteworthy impact on the improvement of light-induced charge-separation. This article describes how the specific compositions of porphyrin chromophores linked to C₆₀—yielding artificial light harvesting antenna and reaction center mimics—have been elegantly utilized to tune the electronic couplings between donor and acceptor sites and the total reorganization energy. Specifically, the effects that these parameters have on the rate, yield and lifetime of the energetic charge-separated states are considered.