Issue 1, 2002

A novel ribbon-candy-like supramolecular architecture of cadmium(ii)–terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8210-a net

Abstract

The hydrothermal reaction of H2tp (tp= terephthalate), [Ph3PCH2Ph]Cl and water with Cd(O2CCH3)2·2H2O gives rise to a novel ribbon-candy-like supramolecular architecture with twofold interpenetration of an unprecedented 3D 8210-a net formed by polymer {[Ph3PCH2Ph][Cd(tp)·Cl]·2H2O}n containing giant rhombic channels, which displays strong fluorescent emission in the solid state.

Supplementary files

Article information

Article type
Communication
Submitted
24 Aug 2001
Accepted
16 Nov 2001
First published
13 Dec 2001

Chem. Commun., 2002, 12-13

A novel ribbon-candy-like supramolecular architecture of cadmium(II)–terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8210-a net

J. Dai, X. Wu, Z. Fu, S. Hu, W. Du, C. Cui, L. Wu, H. Zhang and R. Sun, Chem. Commun., 2002, 12 DOI: 10.1039/B107592F

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