Issue 24, 2001
From the journal:

Chemical Communications

Reactions of quadruply chelated silyl– and germyl–molybdenum hydrido complexes with carboxylic acids and carbon dioxide: a first example of carbon dioxide fixation utilizing the trans effect of a silylligand

Makoto Minato,a   Da-Yang Zhou,a   Ken-ichiro Sumiura,a   Ryo Hirabayashi,a   Yoshitaka Yamaguchia  and  Takashi Ito*a  

* Corresponding authors

a Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, Japan
E-mail: t-ito@ynu.ac.jp

Abstract

The reaction of molybdenum complexes [MoH3{E(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}] (E = Si or Ge) with carboxylic acids gave carboxylato complexes where the carboxylato ligand coordinates to the metal in a unidentate mode; the formato complex was found to be an effective catalyst for carbon dioxide fixation.

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Article information

DOI
https://doi.org/10.1039/B107837M
Article type
Communication
Submitted
30 Aug 2001
Accepted
07 Nov 2001
First published
04 Dec 2001

Chem. Commun., 2001, 2654-2655

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Reactions of quadruply chelated silyl– and germyl–molybdenum hydrido complexes with carboxylic acids and carbon dioxide: a first example of carbon dioxide fixation utilizing the trans effect of a silyl ligand

M. Minato, D. Zhou, K. Sumiura, R. Hirabayashi, Y. Yamaguchi and T. Ito, Chem. Commun., 2001, 2654 DOI: 10.1039/B107837M

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