Issue 23, 2001
From the journal:

Chemical Communications

Silver(i) carboxylates: versatile inorganic analogs of carboxylic acids for supramolecular network formationElectronic supplementary information (ESI) available: synthesis, characterization and crystal data for 1–3; displacement ellipsoid plots; figures showing carboxylate coordination modes. See http://www.rsc.org/suppdata/cc/b1/b108448h/

Lee Brammer,‡*a   Michael D. Burgard,a   Colin S. Rodger,a   John K. Swearingena  and  Nigam P. Ratha  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Missouri–St. Louis, 8001 Natural Bridge Road, St. Louis, MO, USA

Abstract

Dimeric motifs formed by silver(I) carboxylates, illustrated here by the unit Ag2(CF3CO2)2, resemble the well known dimerization of carboxylic acids, i.e. ‘H2(RCO2)2’, but exhibit greater flexibility, while permitting further elaboration into neutral coordination networks through linkage of the silver centres via ditopic ligands.

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Article information

DOI
https://doi.org/10.1039/B108448H
Article type
Communication
Submitted
18 Sep 2001
Accepted
16 Oct 2001
First published
15 Nov 2001

Chem. Commun., 2001, 2468-2469

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Silver(I) carboxylates: versatile inorganic analogs of carboxylic acids for supramolecular network formation

L. Brammer, M. D. Burgard, C. S. Rodger, J. K. Swearingen and N. P. Rath, Chem. Commun., 2001, 2468 DOI: 10.1039/B108448H

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