Abstract

Fully dense polycrystalline Ti₃AlC₂ was fabricated by a solid–liquid reaction synthesis and simultaneous in-situ hot pressing of a mixture of Ti, Al and graphite powders at 1500 °C and 25 MPa for 5 minutes and subsequently annealing at 1200 °C for 20 minutes. The effects of various parameters including composition of the initial elemental powders, temperature as well as the hot pressing pressure on the purity, formation and densification of Ti₃AlC₂ were examined. In addition, the reaction path for the formation of Ti₃AlC₂ was investigated by DTA, XRD, SEM and EDS, suggesting that the reaction path during the heating process could be reasonably described as follows: Al powder melted at some 660 °C and coated the Ti particles; at about 740 °C the exothermic reactions between Al and Ti occurred and Ti–Al intermetallics like TiAl and Ti₃Al were formed; the diffusion of carbon in the Ti–Al intermetallics at elevated temperature resulted in the carbides Ti₂AlC, Ti₃AlC and TiC; and finally these carbides and the unreacted graphite reacted at about 1420 °C to yield Ti₃AlC₂.