Issue 1, 2002

A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

Abstract

The novel and highly β-stereoselective glycosidations of a 2-iodo-olivosyl fluoride and alcohols using a heterogeneous and environmentally benign solid acid, montmorillonite K-10, have been developed to afford the corresponding 2-iodo-β-olivosides in high yields with high stereoselectivities.

Graphical abstract: A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

Article information

Article type
Paper
Submitted
09 Oct 2002
First published
14 Jan 2002

Green Chem., 2002,4, 27-29

A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

K. Toshima, K. Uehara, H. Nagai and S. Matsumura, Green Chem., 2002, 4, 27 DOI: 10.1039/B109172G

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