Issue 4, 2002

Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a Ptii diimine chromophore

Abstract

This is the first report describing the use of picosecond time-resolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4′-(CO2Et)2-2,2′-bpy)Cl2: monitoring changes in the ν(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

Graphical abstract: Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a Ptii diimine chromophore

Article information

Article type
Communication
Submitted
31 Oct 2001
Accepted
09 Jan 2002
First published
30 Jan 2002

Chem. Commun., 2002, 382-383

Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore

J. A. Weinstein, D. C. Grills, M. Towrie, P. Matousek, A. W. Parker and M. W. George, Chem. Commun., 2002, 382 DOI: 10.1039/B109919A

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