Vibrational spectroscopy of tetrahedral ternary metal hydrides: Mg2NiH4, Rb3ZnH5 and their deuterides

Stewart F.  Parker; Kenneth P. J.  Williams; Tim Smith; Manfred Bortz; Bernard Bertheville; Klaus Yvon

doi:10.1039/B109975B

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Vibrational spectroscopy of tetrahedral ternary metal hydrides: Mg₂NiH_4, Rb₃ZnH₅ and their deuterides†

Stewart F. Parker,*^a Kenneth P. J. Williams,^b Tim Smith,^b Manfred Bortz,^c Bernard Bertheville^c and Klaus Yvon^c

Author affiliations

* Corresponding authors

^a ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon, UK
E-mail: S.F.Parker@rl.ac.uk
Fax: +44 (0)1235 445720

^b Transducer System Division, Renishaw plc, Old Town, Wotton-under-Edge, Gloucestershire, UK

^c Laboratoire de Cristallographie, Université de Genève, 24 quai Ernest Ansermet, Geneva 4, Switzerland

Abstract

The infrared, Raman and inelastic neutron scattering spectra of the approximately tetrahedral ternary metal hydrides: Mg₂NiH₄, Rb₃ZnH₅ and their deuterides have been observed and assigned. This has enabled a comparison of some of the properties of the first row transition ternary metal hydrides.

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Article information

DOI: https://doi.org/10.1039/B109975B
Article type: Paper
Submitted: 01 Nov 2001
Accepted: 07 Jan 2002
First published: 08 Apr 2002

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Phys. Chem. Chem. Phys., 2002,4, 1732-1737

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Vibrational spectroscopy of tetrahedral ternary metal hydrides: Mg₂NiH_4, Rb₃ZnH₅ and their deuterides

S. F. Parker, K. P. J. Williams, T. Smith, M. Bortz, B. Bertheville and K. Yvon, Phys. Chem. Chem. Phys., 2002, 4, 1732 DOI: 10.1039/B109975B

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