Issue 9, 2002

Photo-induced ligand substitution at a remote site viaelectron transfer in a porphyrin-appended rhenium carbonyl supermolecule

Abstract

The photochemical and electrochemical properties of a Zn-porphyrin appended rhenium(I) tricarbonyl bipyridine 3-Me-pyridine complex have been investigated; visible-light sensitisation of electron transfer results in ligand substitution at a site remote from the chromophore.

Graphical abstract: Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule

Supplementary files

Article information

Article type
Communication
Submitted
03 Jan 2002
Accepted
06 Mar 2002
First published
02 Apr 2002

Chem. Commun., 2002, 950-951

Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule

A. Gabrielsson, F. B. src="https://www.rsc.org/images/entities/char_0073_0306.gif" A. W. C. B. xmlns="http://www.rsc.org/schema/rscart38" /. Hartl, J. R. L. Smith and R. N. Perutz, Chem. Commun., 2002, 950 DOI: 10.1039/B200127F

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