Issue 6, 2002
From the journal:

Chemical Communications

Unique crown thioether complexes of f elements: the crystal structure of U(iii) and La(iii) complexes of 1,4,7-trithiacyclononane

Lydia Karmazin,a   Marinella Mazzanti*a  and  Jacques Pécautb  

* Corresponding authors

a Laboratoire de Reconnaissance Ionique, Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, 17 rue des Martyrs, Grenoble, Cedex 09, France
E-mail: mazzanti@drfmc.ceng.cea.fr

b Laboratoire de Coordination et Chiralité, Service de Chimie Inorganique et Biologique, Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, 17 rue des Martyrs, Grenoble, Cedex 09, France

Abstract

The crystal structures of the first U(III) complex of a crown thioether and of its La(III) analog have been determined; a stronger M–S interaction is observed for U(III) with respect to La(III) and Ce(III) in solution and in the solid state.

Graphical abstract: Unique crown thioether complexes of f elements: the crystal structure of U(iii) and La(iii) complexes of 1,4,7-trithiacyclononane

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Article information

DOI
https://doi.org/10.1039/B200315P
Article type
Communication
Submitted
08 Jan 2002
Accepted
08 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 654-655

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Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane

L. Karmazin, M. Mazzanti and J. Pécaut, Chem. Commun., 2002, 654 DOI: 10.1039/B200315P

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