Issue 13, 2002
From the journal:

Chemical Communications

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions†

Jun Tao,ab   Yong Zhang,a   Ming-Liang Tong,a   Xiao-Ming Chen,*a   Tan Yuen,c   C. L. Lin,c   Xiaoying Huangd  and  Jing Lid  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, China

b School of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: cescxm@zsu.edu.cn

c Department of Physics, Temple University, Philadelphia, Pennsylvania, USA

d Department of Chemistry, Rutgers University, Piscataway, New Jersey, USA

Abstract

A novel coordination polymer of mixed-valence copper(I,II) with 4,4′-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4′-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)–oxygen interactions.

Graphical abstract: A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions

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Article information

DOI
https://doi.org/10.1039/B203301A
Article type
Communication
Submitted
04 Apr 2002
Accepted
09 May 2002
First published
21 May 2002

Chem. Commun., 2002, 1342-1343

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A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions

J. Tao, Y. Zhang, M. Tong, X. Chen, T. Yuen, C. L. Lin, X. Huang and J. Li, Chem. Commun., 2002, 1342 DOI: 10.1039/B203301A

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