Issue 14, 2002
From the journal:

Chemical Communications

An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(ii) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block†

Patrick Gamez,*a   Paul de Hoog,a   Olivier Roubeau,a   Martin Lutz,b   Willem L. Driessen,a   Anthony L. Spekb  and  Jan Reedijk*a  

* Corresponding authors

a Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, Leiden, The Netherlands
E-mail: reedijk@chem.leidenuniv.nl, p.gamez@chem.leidenuniv.nl

b Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, Utrecht, The Netherlands

Abstract

Copper(II) nitrate reacts with the rigid polydentate triple-connecting dpyatriz ligand in acetonitrile to an unprecedented infinite molecular ladder in which five-coordinated copper pseudo-dimers are bridged by nitrate anions and the coordination polymer chains are linked by hexacoordinated copper ions leading to the formation of large guest cavities.

Graphical abstract: An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(ii) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B203394A
Article type
Communication
Submitted
09 Apr 2002
Accepted
28 May 2002
First published
11 Jun 2002

Chem. Commun., 2002, 1488-1489

Permissions

Request permissions

An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(II) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block

P. Gamez, P. D. Hoog, O. Roubeau, M. Lutz, W. L. Driessen, A. L. Spek and J. Reedijk, Chem. Commun., 2002, 1488 DOI: 10.1039/B203394A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements