Issue 15, 2002
From the journal:

Chemical Communications

Benzyl anion abstraction from a (β-diiminato)Fe(ii) benzyl complex†

Timo J.J. Sciarone,a   Auke Meetsma,a   Bart Hesssen*a  and  Jan H. Teubena  

* Corresponding authors

a Dutch Polymer Institute/Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands
E-mail: hessen@chem.rug.nl
Fax: (+31)50 363 4315
Tel: (+31)50 363 4322

Abstract

The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)Fe(CH2Ph)] reacts with B(C6F5)3 to yield a paramagnetic contact ion pair with an η2-(o,m)-[PhCH2B(C6F5)3] anion, which was characterised by X-ray diffraction.

Graphical abstract: Benzyl anion abstraction from a (β-diiminato)Fe(ii) benzyl complex

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Article information

DOI
https://doi.org/10.1039/B204454D
Article type
Communication
Submitted
05 May 2002
Accepted
05 Jun 2002
First published
21 Jun 2002

Chem. Commun., 2002, 1580-1581

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Benzyl anion abstraction from a (β-diiminato)Fe(II) benzyl complex

T. J.J. Sciarone, A. Meetsma, B. Hesssen and J. H. Teuben, Chem. Commun., 2002, 1580 DOI: 10.1039/B204454D

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