[Fe2(C10O8H2)]: An antiferromagnetic 3D iron(II) carboxylate built from ferromagnetic edge-sharing octahedral chains (MIL-62)

M. Sanselme; J. M. Grenèche; M. Riou-Cavellec; G. Férey

doi:10.1039/B206141D

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[Fe₂(C₁₀O₈H₂)]: An antiferromagnetic 3D iron(ii) carboxylate built from ferromagnetic edge-sharing octahedral chains (MIL-62)

M. Sanselme,^a J. M. Grenèche,^b M. Riou-Cavellec*^a and G. Férey*^ac

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* Corresponding authors

^a Institut Lavoisier (UMR CNRS 8637), 45 avenue des Etats-Unis, 78035, Versailles Cedex, France
E-mail: cavellec@chimie.uvsq.fr
Fax: +33 1 39 25 43 58

^b Laboratoire de Physique de l’Etat Condensé (UMR CNRS 6087), Université du Maine, Avenue O. Messiaen, 72085, Le Mans Cedex 9, France

^c Institut Universitaire de France, 103 bld. Saint Michel, Paris, France

Abstract

The first three-dimensional iron(II) tetracarboxylate is built from the connection of chains of edge-sharing Fe(II) octahedra by 1,2,4,5-benzenetetracarboxylates; magnetic measurements show an antiferromagnetic coupling of ferromagnetic chains below T_N = 25(1) K.

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Supplementary files

Crystal structure data TXT (10K)

Article information

DOI: https://doi.org/10.1039/B206141D
Article type: Communication
Submitted: 26 Jun 2002
Accepted: 25 Jul 2002
First published: 27 Aug 2002

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Chem. Commun., 2002, 2172-2173

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[Fe₂(C₁₀O₈H₂)]: An antiferromagnetic 3D iron(II) carboxylate built from ferromagnetic edge-sharing octahedral chains (MIL-62)

M. Sanselme, J. M. Grenèche, M. Riou-Cavellec and G. Férey, Chem. Commun., 2002, 2172 DOI: 10.1039/B206141D

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