Issue 23, 2002

Routes to fluorinated organic derivatives by nickel mediated C–F activation of heteroaromatics

Abstract

New fluorinated azaheterocycles can be synthesised regio- and chemo-selectively via C–F activation of fluorinated precursors at nickel, with subsequent functionalisation and release from the coordination sphere of the metal; the requirements for productive C–F activation are significantly different from those for C–H bond activation.

Article information

Article type
Feature Article
Submitted
27 Jun 2002
Accepted
12 Sep 2002
First published
11 Oct 2002

Chem. Commun., 2002, 2749-2757

Routes to fluorinated organic derivatives by nickel mediated C–F activation of heteroaromatics

T. Braun and R. N. Perutz, Chem. Commun., 2002, 2749 DOI: 10.1039/B206154F

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