Issue 20, 2002
From the journal:

Chemical Communications

Structure of low concentrations of vanadium on TiO2 determined by XANES and ab initio calculations

Yasuo Izumi,*a   Fumitaka Kiyotaki,a   Hideaki Yoshitake,b   Ken-ichi Aika,a   Tae Sugihara,c   Takashi Tatsumi,c   Yasuhiro Tanizawa,d   Takafumi Shidod  and  Yasuhiro Iwasawad  

* Corresponding authors

a Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan
E-mail: izumi@chemenv.titech.ac.jp

b Graduate School of Environment and Information Sciences, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501, Japan

c Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501, Japan

d Graduate School of Science, The University of Tokyo, Bunkyo-ku, Hongo 113-0033, Japan

Abstract

The major local structure of low concentrations (1–3 wt% V) of vanadium on TiO2 was determined to have two terminal oxo groups and in total five oxygen coordination by means of vanadium K-edge XANES and ab initio calculations of XANES spectra.

Graphical abstract: Structure of low concentrations of vanadium on TiO2 determined by XANES and ab initio calculations

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Article information

DOI
https://doi.org/10.1039/B207159B
Article type
Communication
Submitted
24 Jul 2002
Accepted
06 Sep 2002
First published
20 Sep 2002

Chem. Commun., 2002, 2402-2403

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Structure of low concentrations of vanadium on TiO2 determined by XANES and ab initio calculations

Y. Izumi, F. Kiyotaki, H. Yoshitake, K. Aika, T. Sugihara, T. Tatsumi, Y. Tanizawa, T. Shido and Y. Iwasawa, Chem. Commun., 2002, 2402 DOI: 10.1039/B207159B

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