Issue 22, 2002

Novel generation of an o-quinone methide from 2-(2′-cyclohexenyl)phenol by excited state intramolecular proton transfer and subsequent C–C fragmentation

Abstract

Formation of an o-quinone methide via C–C fragmentation of a zwitterion formed by intramolecular excited state proton transfer from an o-allylphenol derivative is reported for the first time.

Graphical abstract: Novel generation of an o-quinone methide from 2-(2′-cyclohexenyl)phenol by excited state intramolecular proton transfer and subsequent C–C fragmentation

Article information

Article type
Communication
Submitted
01 Aug 2002
Accepted
01 Oct 2002
First published
10 Oct 2002

Chem. Commun., 2002, 2636-2637

Novel generation of an o-quinone methide from 2-(2′-cyclohexenyl)phenol by excited state intramolecular proton transfer and subsequent C–C fragmentation

J. Delgado, A. Espinós, M. C. Jiménez and M. A. Miranda, Chem. Commun., 2002, 2636 DOI: 10.1039/B207545H

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