Issue 22, 2002
From the journal:

Chemical Communications

Unprecedented host-induced intramolecular charge-transfer complex formation†

Jae Wook Lee,a   Kyungpil Kim,a   SooWhan Choi,a   Young Ho Ko,a   Shigeru Sakamoto,b   Kentaro Yamaguchib  and  Kimoon Kim*a  

* Corresponding authors

a National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang, Republic of Korea
E-mail: kkim@postech.ac.kr
Fax: (+82)54-279-8129

b Chemical Analysis Center, Chiba University, 1-33 Yayoicho, Inageku, Chiba, Japan

Abstract

For the first time, host-induced intramolecular charge-transfer complex formation in a guest containing both an electron donor and an electron acceptor is demonstrated in the cucurbit[8]uril cavity, leading to unusual back-folding of the guest molecule.

Graphical abstract: Unprecedented host-induced intramolecular charge-transfer complex formation

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Article information

DOI
https://doi.org/10.1039/B208280B
Article type
Communication
Submitted
27 Aug 2002
Accepted
02 Oct 2002
First published
21 Oct 2002

Chem. Commun., 2002, 2692-2693

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Unprecedented host-induced intramolecular charge-transfer complex formation

J. W. Lee, K. Kim, S. Choi, Y. H. Ko, S. Sakamoto, K. Yamaguchi and K. Kim, Chem. Commun., 2002, 2692 DOI: 10.1039/B208280B

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