Issue 1, 2003
From the journal:

Chemical Communications

A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)†

Hidetaka Nakai,a   Yongjun Tang,a   Peter Gantzela  and  Karsten Meyer*a  

* Corresponding authors

a University of California, San Diego, Department of Chemistry and Biochemistry, La Jolla, CA, USA
E-mail: kmeyer@ucsd.edu

Abstract

The synthesis and characterisation of a thallium(I) triscarbene complex of the chelating, tripodal carbene ligand 1,3,5-{tris(3-tert-butylimidazol-2-ylideno)methyl}-2,4,6-trimethylbenzene is reported, in which the thallium ion is coordinated by three N-heterocyclic carbene donors in a distorted trigonal planar environment.

Graphical abstract: A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)

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Article information

DOI
https://doi.org/10.1039/B209071F
Article type
Communication
Submitted
17 Sep 2002
Accepted
28 Oct 2002
First published
26 Nov 2002

Chem. Commun., 2003, 24-25

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A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(I)

H. Nakai, Y. Tang, P. Gantzel and K. Meyer, Chem. Commun., 2003, 24 DOI: 10.1039/B209071F

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