Issue 24, 2002
From the journal:

Chemical Communications

A novel dicationic phenoxaphosphino-modified Xantphos-type ligand—a unique ligand specifically designed for a high activity, selectivity and recyclability†

Raymond P. J. Bronger,a   Silvana M. Silva,b   Paul C. J. Kamera  and  Piet W. N. M. van Leeuwen*a  

* Corresponding authors

a Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, The Netherlands
E-mail: pwnm@science.uva.nl
Fax: +31(0)205256456

b Laboratory of Molecular Catalysis, Instituto de Quimica, UFRGS, Av. Bento Gonçalves, 9500, Porto Alegre, Brazil

Abstract

A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments.

Graphical abstract: A novel dicationic phenoxaphosphino-modified Xantphos-type ligand—a unique ligand specifically designed for a high activity, selectivity and recyclability

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Article information

DOI
https://doi.org/10.1039/B209486J
Article type
Communication
Submitted
01 Oct 2002
Accepted
25 Oct 2002
First published
15 Nov 2002

Chem. Commun., 2002, 3044-3045

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A novel dicationic phenoxaphosphino-modified Xantphos-type ligand—a unique ligand specifically designed for a high activity, selectivity and recyclability

R. P. J. Bronger, S. M. Silva, P. C. J. Kamer and P. W. N. M. V. Leeuwen, Chem. Commun., 2002, 3044 DOI: 10.1039/B209486J

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