Issue 2, 2003
From the journal:

Chemical Communications

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)†

Dina N. Akbayeva,a   Luca Gonsalvi,a   Werner Oberhauser,a   Maurizio Peruzzini,*a   Francesco Vizza,*a   Peter Brüggeller,b   Antonio Romerosa,c   Gianni Savad  and  Alberta Bergamod  

* Corresponding authors

a Istituto di Chimica dei Composti Organometallici, ICCOM-CNR, Via Jacopo Nardi 39, 50132 Firenze, Italy
E-mail: peruz@fi.cnr.it, vizza@fi.cnr.it
Fax: +39 055 2478366
Tel: +39 055 245990

b Institut für Allgemeine, Anorganische und Theoretische Chemie der Universität Innsbruck, Innsbruck, Austria

c Área de Quimica Inorganica, Universidad de Almería, Almería, Spain

d Callerio Foundation Onlus, Via Fleming 22–31, 34127 Trieste, Italy

Abstract

The new water soluble ruthenium complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) were synthesised and characterised. Their evaluation as regioselective catalysts for hydrogenation of unsaturated ketones in aqueous biphasic conditions and as cytotoxic agents towards the TS/A adenocarcinoma cell line is briefly presented.

Graphical abstract: Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)

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Article information

DOI
https://doi.org/10.1039/B210102E
Article type
Communication
Submitted
15 Oct 2002
Accepted
25 Nov 2002
First published
18 Dec 2002

Chem. Commun., 2003, 264-265

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Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)

D. N. Akbayeva, L. Gonsalvi, W. Oberhauser, M. Peruzzini, F. Vizza, P. Brüggeller, A. Romerosa, G. Sava and A. Bergamo, Chem. Commun., 2003, 264 DOI: 10.1039/B210102E

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