Issue 1, 2003
From the journal:

Chemical Communications

Ni(ii) Complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins

Luca Fadinia  and  Antonio Togni*a  

* Corresponding authors

a Department of Chemistry, Swiss Federal Institute of Technology, ETH Hönggerberg, CH-8093 Zürich, Switzerland
E-mail: togni@inorg.chem.ethz.ch
Fax: +41 1 6321310

Abstract

Ni(II) complexes containing chiral tridentate ferrocenyl phosphines (Ni(PPP)) have been found to efficiently catalyse the hydroamination of activated olefins with both anilines and aliphatic amines at r.t. (TON up to 71, TOF up to ca. 3 h−1, and enantioselectivities up to 69% ee).

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Article information

DOI
https://doi.org/10.1039/B210680A
Article type
Communication
Submitted
30 Oct 2002
Accepted
11 Nov 2002
First published
25 Nov 2002

Chem. Commun., 2003, 30-31

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Ni(II) Complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins

L. Fadini and A. Togni, Chem. Commun., 2003, 30 DOI: 10.1039/B210680A

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